Yes.

[She's not really trying to impress or cause anyone to feel inferior. It's a simple facet of the matter that she is a senator and has been for some time now.

It's not hard to see that she's made him uncomfortable and she goes to give a friendly smile as she answers his question.]

Hm, I do believe that senator is a job title and can be used in place of another such title. However, you can just call me Padmé.